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 In the UK, are there any additional costs like licences, royalties on music items etc

To be legal within the UK you do need two licenses, one PPL and one from MCPS see a forum post...

 US Radio Royalty Licenses

For your Internet radio Royalty Licensing you should contact one of the companies below for that...

 ZoeCast royalty/broadcast reports

Broadcast Reports Centova Cast's track broadcast reports are downloadable (CSV-format)...